Фролова Любовь Анатольевна, руководитель группы

Ученая степень к.х.н.

тел.: +7 496 522-18-63

e-mail: lyubovanatolievna@mail.ru

Научные интересы

Разработка различных типов тонкопленочной электроники: гибридных и неорганических перовскитных солнечных батарей, фотодетекторов,  устройств памяти на основе органических полевых транзисторов

 Достижения

Соавтор более чем 80 статей в высокорейтинговых международных и российских научных журналах. Сделала более 50 устных и приглашенных докладов на международных научных конференциях и школах. Руководила двумя грантами РФФИ, тремя проектами Министерства науки и высшего образования РФ и тремя грантами Российского научного фонда, два из них находятся в процессе реализации.

Была руководителем >20 дипломных работ студентов и 2 аспирантов.

Индекс Хирша h=22 (Web of Science), h=22 (Scopus), h=22 (Google Scholar)

Список публикаций

Соавтор более чем 80 статей в высокорейтинговых международных и российских научных журналах.

Избранные публикации:

  1. M. K. Kuznetsov, N. A. Emelianov, D. V. Korchagin, G. V. Shilov, S. M. Aldoshin, P. A. Troshin and L. A. Frolova, Photostability of CsPbI2Br-based Perovskite Solar Cells through suppression of the phase segregation using a zwitterionic additive. Sustain. Energy Fuels2022, DOI:10.1039/D2SE00450J.
  2. O. Kraevaya, A. Latypova, A. A. Sokolova, A. A. Seleznyova, N. A. Emelianov, N. A. Slesarenko, V. Y. Markov, L. Frolova and P. Troshin, Oxidative polymerization of triarylamines: a promising route to low-cost hole transport materials for efficient perovskite solar cells. Sustain. Energy Fuels2022, DOI:10.1039/D2SE00492E.
  3. L. A. Frolova, Y. Furmansky, A. F. Shestakov, N. A. Emelianov, P. A. Liddell, D. Gust, I. Visoly-Fisher and P. A. Troshin, Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads. ACS Appl. Mater. Interfaces2022, 14, 15461–15467.
  4. E. Komissarova, S. A. Kuklin, A. Maskaev, A. Latypova, P. Kuznetsov, N. A. Emelianov, S. L. Nikitenko, I. Martynov, I. E. Kuznetsov, A. V. Akkuratov, L. Frolova and P. Troshin, Novel benzodithiophene-TBTBT copolymers: synthesis and investigation in organic and perovskite solar cells. Sustain. Energy Fuels2022, DOI:10.1039/D2SE00463A.
  5. N. A. Emelianov, V. V. Ozerova, I. S. Zhidkov, D. V. Korchagin, G. V. Shilov, A. L. Litvinov, E. Z. Kurmaev, L. A. Frolova, S. M. Aldoshin and P. A. Troshin, Nanoscale Visualization of Photodegradation Dynamics of MAPbI3 Perovskite Films J. Phys. Chem. Lett., 2022, 13, 2744–2749.
  6. M. M. Elnaggar, L. G. Gutsev, N. A. Emelianov, P. M. Kuznetsov, L. A. Frolova, S. M. Aldoshin and P. A. Troshin, Molecular Engineering of Polytriarylamine-Based Hole-Transport Materials for p–i–n Perovskite Solar Cells: Methyl Groups Matter. ACS Appl. Energy Mater2022, 5, 5388–5394.
  7. A. F. Latypova, N. A. Emelianov, D. O. Balakirev, P. K. Sukhorukova, N. K. Kalinichenko, P. M. Kuznetsov, Y. N. Luponosov, S. M. Aldoshin, S. A. Ponomarenko, P. A. Troshin and L. A. Frolova, Design Principles for Organic Small Molecule Hole-Transport Materials for Perovskite Solar Cells: Film Morphology Matters. ACS Appl. Energy Mater., 2022, 5, 5395–5403.
  8. A. Elakshar, S. Tsarev, P. M. Rajanna, M. Tepliakova, L. Frolova, Y. G. Gladush, S. M. Aldoshin, P. A. Troshin and A. G. Nasibulin, Surface Passivation for Efficient Bifacial HTL-free Perovskite Solar Cells with SWCNT Top Electrodes. ACS Appl. Energy Mater., 2021, 4, 13395–13400.
  9. I. S. Zhidkov, A. F. Akbulatov, L. N. Inasaridze, A. I. Kukharenko, L. A. Frolova, S. O. Cholakh, C.-C. Chueh, P. A. Troshin and E. Z. Kurmaev, Influence of Oxygen Ion Migration from Substrates on Photochemical Degradation of CH3NH3PbI3 Hybrid Perovskite. Energies2021, 14, 5062.
  10. A. F. Akbulatov, M. I. Ustinova, G. V. Shilov, N. N. Dremova, I. S. Zhidkov, E. Z. Kurmaev, L. A. Frolova, A. F. Shestakov, S. M. Aldoshin and P. A. Troshin, Temperature Dynamics of MAPbI3 and PbI2 Photolysis: Revealing the Interplay between Light and Heat, Two Enemies of Perovskite Photovoltaics. J. Phys. Chem. Lett., 2021, 12, 4362–4367.
  11. L. A. Frolova, L. G. Gutsev, B. R. Ramachandran, N. N. Dremova, S. M. Aldoshin and P. A. Troshin, Exploring CsPbI3 – FAI alloys: Introducing low-dimensional Cs2FAPb2I7 absorber for efficient and stable perovskite solar cells. Chem. Eng. Sci.2021, 426, 131754
  12. A. F. Akbulatov, M. I. Ustinova, L. Gutsev, S. A. Tsarev, N. N. Dremova, I. Zhidkov, S. Yu. Luchkin, B. R. Ramachandran, L. A. Frolova, E. Z. Kurmaev, K. J. Stevenson, S. M. Aldoshin, P. A. Troshin. When iodide meets bromide: halide mixing facilitates light-induced decomposition of perovskite absorber films. Nano Energy, 2021, 86, 106082
  13. L. A. Frolova, S. Yu. Luchkin, Y. Lekina, S. A. Tsarev, I. Zhidkov, E. Z. Kurmaev, Z. X. Shen, K. J. Stevenson, S. M. Aldoshin, P. A. Troshin. Reversible Pb2+/Pb0 and I/I3 redox chemistry drives the light-induced phase segregation in all-inorganic mixed halide perovskites. Adv. Energy Mater., 2021, 11, 2002934
  14. I. S. Zhidkov, D. W. Boukhvalov, A. F. Akbulatov, L. A. Frolova, L. D. Finkelstein, A. I. Kukharenko, S. O. Cholakh, C-C. Chueh, P. A. Troshin, E. Z. Kurmaev. XPS spectra as a tool for studying photochemical and thermal degradation in APbX3 hybrid halide perovskites. Nano Energy2021, 79, 105421
  15. V. V. Ozerova, I. S. Zhidkov, A. Boldyreva, N. N. Dremova, N. A. Emelianov, G. V. Shilov, L. A. Frolova, E. Z. Kurmaev, A. Y. Sukhorukov, S. M. Aldoshin and P. A. Troshin, Spectacular Enhancement of the Thermal and Photochemical Stability of MAPbI3 Perovskite Films Using Functionalized Tetraazaadamantane as a Molecular Modifier. Energies2021, 14, 669.
  16. M. I. Ustinova, M. M. Mikheeva, G. V. Shilov, N. N. Dremova, L. A. Frolova, S. M. Aldoshin, K. J. Stevenson, P. A. Troshin. Partial substitution of Pb2+ in CsPbI3 as an efficient strategy to design fairly stable all-inorganic perovskite formulations. ACS Appl. Mater. Interfaces2021, 13, 5184–5194
  17. I. V. Klimovich, A. V. Zhilenkov, L. I. Кuznetsova, L. A. Frolova, O. R. Yamilova, S. I. Troyanov, K. A. Lyssenko, P. A. Troshin. Novel functionalized indigo derivatives for organic electronics. Dyes and Pigments2021, 186, 108966
  18. L. A. Frolova, A. I. Davlethanov, N. N. Dremova, A. F. Akbulatov, E. Z. Kurmaev, S. M. Aldoshin, K. J. Stevenson, I. Zhidkov, P. A. Troshin. Efficient and Stable MAPbI3-based Perovskite Solar Cells Using Polyvinylcarbazole Passivation. J. Phys. Chem. Lett.2020, 11, 16, 6772–6778
  19. M. M. Tepliakova, A. N. Miheeva, L. A. Frolova, A. G. Boldyreva, A. Elakshar, A. V. Novikov, S. A. Tsarev, M. I. Ustinova, O. R. Yamilova, A. G. Nasibullin, S. M. Aldoshin, K. J. Stevenson, P. A. Troshin. Incorporation of vanadium (V) oxide in hybrid hole transport layer enables long-term operational stability of perovskite solar cells. J. Phys. Chem. Lett.2020, 11, 5563–5568
  20. A. G. Boldyreva, L. A. Frolova, I. S. Zhidkov, L. G. Gutsev, E. Z. Kurmaev, B. R. Ramachandran, V. G. Petrov, K. J. Stevenson, S. M. Aldoshin and P. A. Troshin, Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI3 Breaks the Records. J. Phys. Chem. Lett.2020, 11, 2630–2636.
  21. A. F. Akbulatov, L. A. Frolova, N. N. Dremova, I. Zhidkov, V. M. Martynenko, S. A. Tsarev, S. Y. Luchkin, E. Z. Kurmaev, S. M. Aldoshin, K. J. Stevenson and P. A. Troshin, Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions? J. Phys. Chem. Lett.2020, 11, 333–339.
  22. S. Tsarev, I. K. Yakushchenko, S. Y. Luchkin, P. M. Kuznetsov, R. S. Timerbulatov, N. N. Dremova, L. A. Frolova, K. J. Stevenson and P. A. Troshin, A new polytriarylamine derivative for dopant-free high-efficiency perovskite solar cells. Sustainable Energy & Fuels2019, 3, 2627–2632.
  23. D. D. Dashitsyrenova, A. G. Lvov, L. A. Frolova, A. V. Kulikov, N. N. Dremova, V. Z. Shirinian, S. M. Aldoshin, M. M. Krayushkin and P. A. Troshin, Molecular structure–electrical performance relationship for OFET-based memory elements comprising unsymmetrical photochromic diarylethenes. J. Mater. Chem. C20197, 6889–6894.
  24. L. A. Frolova, Q. Chang, S. Yu. Luchkin, D. Zhao, A. F. Akbulatov, N. N. Dremova, A. V. Ivanov, E.E. M. Chia, K. J. Stevenson and P. A. Troshin. Efficient and stable all-inorganic perovskite solar cells based on nonstoichiometric CsxPbI2Brx (x > 1) alloys. J. Mater. Chem. C2019, 7, 5314-5323.

Ученая степень к.х.н.

тел.: +7 496 522-18-63

e-mail: lyubovanatolievna@mail.ru

Научные интересы

Разработка различных типов тонкопленочной электроники: гибридных и неорганических перовскитных солнечных батарей, фотодетекторов,  устройств памяти на основе органических полевых транзисторов

 Достижения

Соавтор более чем 80 статей в высокорейтинговых международных и российских научных журналах. Сделала более 50 устных и приглашенных докладов на международных научных конференциях и школах. Руководила двумя грантами РФФИ, тремя проектами Министерства науки и высшего образования РФ и тремя грантами Российского научного фонда, два из них находятся в процессе реализации.

Была руководителем >20 дипломных работ студентов и 2 аспирантов.

Индекс Хирша h=22 (Web of Science), h=22 (Scopus), h=22 (Google Scholar)

Список публикаций

Соавтор более чем 80 статей в высокорейтинговых международных и российских научных журналах.

Избранные публикации:

  1. M. K. Kuznetsov, N. A. Emelianov, D. V. Korchagin, G. V. Shilov, S. M. Aldoshin, P. A. Troshin and L. A. Frolova, Photostability of CsPbI2Br-based Perovskite Solar Cells through suppression of the phase segregation using a zwitterionic additive. Sustain. Energy Fuels2022, DOI:10.1039/D2SE00450J.
  2. O. Kraevaya, A. Latypova, A. A. Sokolova, A. A. Seleznyova, N. A. Emelianov, N. A. Slesarenko, V. Y. Markov, L. Frolova and P. Troshin, Oxidative polymerization of triarylamines: a promising route to low-cost hole transport materials for efficient perovskite solar cells. Sustain. Energy Fuels2022, DOI:10.1039/D2SE00492E.
  3. L. A. Frolova, Y. Furmansky, A. F. Shestakov, N. A. Emelianov, P. A. Liddell, D. Gust, I. Visoly-Fisher and P. A. Troshin, Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads. ACS Appl. Mater. Interfaces2022, 14, 15461–15467.
  4. E. Komissarova, S. A. Kuklin, A. Maskaev, A. Latypova, P. Kuznetsov, N. A. Emelianov, S. L. Nikitenko, I. Martynov, I. E. Kuznetsov, A. V. Akkuratov, L. Frolova and P. Troshin, Novel benzodithiophene-TBTBT copolymers: synthesis and investigation in organic and perovskite solar cells. Sustain. Energy Fuels2022, DOI:10.1039/D2SE00463A.
  5. N. A. Emelianov, V. V. Ozerova, I. S. Zhidkov, D. V. Korchagin, G. V. Shilov, A. L. Litvinov, E. Z. Kurmaev, L. A. Frolova, S. M. Aldoshin and P. A. Troshin, Nanoscale Visualization of Photodegradation Dynamics of MAPbI3 Perovskite Films J. Phys. Chem. Lett., 2022, 13, 2744–2749.
  6. M. M. Elnaggar, L. G. Gutsev, N. A. Emelianov, P. M. Kuznetsov, L. A. Frolova, S. M. Aldoshin and P. A. Troshin, Molecular Engineering of Polytriarylamine-Based Hole-Transport Materials for p–i–n Perovskite Solar Cells: Methyl Groups Matter. ACS Appl. Energy Mater2022, 5, 5388–5394.
  7. A. F. Latypova, N. A. Emelianov, D. O. Balakirev, P. K. Sukhorukova, N. K. Kalinichenko, P. M. Kuznetsov, Y. N. Luponosov, S. M. Aldoshin, S. A. Ponomarenko, P. A. Troshin and L. A. Frolova, Design Principles for Organic Small Molecule Hole-Transport Materials for Perovskite Solar Cells: Film Morphology Matters. ACS Appl. Energy Mater., 2022, 5, 5395–5403.
  8. A. Elakshar, S. Tsarev, P. M. Rajanna, M. Tepliakova, L. Frolova, Y. G. Gladush, S. M. Aldoshin, P. A. Troshin and A. G. Nasibulin, Surface Passivation for Efficient Bifacial HTL-free Perovskite Solar Cells with SWCNT Top Electrodes. ACS Appl. Energy Mater., 2021, 4, 13395–13400.
  9. I. S. Zhidkov, A. F. Akbulatov, L. N. Inasaridze, A. I. Kukharenko, L. A. Frolova, S. O. Cholakh, C.-C. Chueh, P. A. Troshin and E. Z. Kurmaev, Influence of Oxygen Ion Migration from Substrates on Photochemical Degradation of CH3NH3PbI3 Hybrid Perovskite. Energies2021, 14, 5062.
  10. A. F. Akbulatov, M. I. Ustinova, G. V. Shilov, N. N. Dremova, I. S. Zhidkov, E. Z. Kurmaev, L. A. Frolova, A. F. Shestakov, S. M. Aldoshin and P. A. Troshin, Temperature Dynamics of MAPbI3 and PbI2 Photolysis: Revealing the Interplay between Light and Heat, Two Enemies of Perovskite Photovoltaics. J. Phys. Chem. Lett., 2021, 12, 4362–4367.
  11. L. A. Frolova, L. G. Gutsev, B. R. Ramachandran, N. N. Dremova, S. M. Aldoshin and P. A. Troshin, Exploring CsPbI3 – FAI alloys: Introducing low-dimensional Cs2FAPb2I7 absorber for efficient and stable perovskite solar cells. Chem. Eng. Sci.2021, 426, 131754
  12. A. F. Akbulatov, M. I. Ustinova, L. Gutsev, S. A. Tsarev, N. N. Dremova, I. Zhidkov, S. Yu. Luchkin, B. R. Ramachandran, L. A. Frolova, E. Z. Kurmaev, K. J. Stevenson, S. M. Aldoshin, P. A. Troshin. When iodide meets bromide: halide mixing facilitates light-induced decomposition of perovskite absorber films. Nano Energy, 2021, 86, 106082
  13. L. A. Frolova, S. Yu. Luchkin, Y. Lekina, S. A. Tsarev, I. Zhidkov, E. Z. Kurmaev, Z. X. Shen, K. J. Stevenson, S. M. Aldoshin, P. A. Troshin. Reversible Pb2+/Pb0 and I/I3 redox chemistry drives the light-induced phase segregation in all-inorganic mixed halide perovskites. Adv. Energy Mater., 2021, 11, 2002934
  14. I. S. Zhidkov, D. W. Boukhvalov, A. F. Akbulatov, L. A. Frolova, L. D. Finkelstein, A. I. Kukharenko, S. O. Cholakh, C-C. Chueh, P. A. Troshin, E. Z. Kurmaev. XPS spectra as a tool for studying photochemical and thermal degradation in APbX3 hybrid halide perovskites. Nano Energy2021, 79, 105421
  15. V. V. Ozerova, I. S. Zhidkov, A. Boldyreva, N. N. Dremova, N. A. Emelianov, G. V. Shilov, L. A. Frolova, E. Z. Kurmaev, A. Y. Sukhorukov, S. M. Aldoshin and P. A. Troshin, Spectacular Enhancement of the Thermal and Photochemical Stability of MAPbI3 Perovskite Films Using Functionalized Tetraazaadamantane as a Molecular Modifier. Energies2021, 14, 669.
  16. M. I. Ustinova, M. M. Mikheeva, G. V. Shilov, N. N. Dremova, L. A. Frolova, S. M. Aldoshin, K. J. Stevenson, P. A. Troshin. Partial substitution of Pb2+ in CsPbI3 as an efficient strategy to design fairly stable all-inorganic perovskite formulations. ACS Appl. Mater. Interfaces2021, 13, 5184–5194
  17. I. V. Klimovich, A. V. Zhilenkov, L. I. Кuznetsova, L. A. Frolova, O. R. Yamilova, S. I. Troyanov, K. A. Lyssenko, P. A. Troshin. Novel functionalized indigo derivatives for organic electronics. Dyes and Pigments2021, 186, 108966
  18. L. A. Frolova, A. I. Davlethanov, N. N. Dremova, A. F. Akbulatov, E. Z. Kurmaev, S. M. Aldoshin, K. J. Stevenson, I. Zhidkov, P. A. Troshin. Efficient and Stable MAPbI3-based Perovskite Solar Cells Using Polyvinylcarbazole Passivation. J. Phys. Chem. Lett.2020, 11, 16, 6772–6778
  19. M. M. Tepliakova, A. N. Miheeva, L. A. Frolova, A. G. Boldyreva, A. Elakshar, A. V. Novikov, S. A. Tsarev, M. I. Ustinova, O. R. Yamilova, A. G. Nasibullin, S. M. Aldoshin, K. J. Stevenson, P. A. Troshin. Incorporation of vanadium (V) oxide in hybrid hole transport layer enables long-term operational stability of perovskite solar cells. J. Phys. Chem. Lett.2020, 11, 5563–5568
  20. A. G. Boldyreva, L. A. Frolova, I. S. Zhidkov, L. G. Gutsev, E. Z. Kurmaev, B. R. Ramachandran, V. G. Petrov, K. J. Stevenson, S. M. Aldoshin and P. A. Troshin, Unravelling the Material Composition Effects on the Gamma Ray Stability of Lead Halide Perovskite Solar Cells: MAPbI3 Breaks the Records. J. Phys. Chem. Lett.2020, 11, 2630–2636.
  21. A. F. Akbulatov, L. A. Frolova, N. N. Dremova, I. Zhidkov, V. M. Martynenko, S. A. Tsarev, S. Y. Luchkin, E. Z. Kurmaev, S. M. Aldoshin, K. J. Stevenson and P. A. Troshin, Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions? J. Phys. Chem. Lett.2020, 11, 333–339.
  22. S. Tsarev, I. K. Yakushchenko, S. Y. Luchkin, P. M. Kuznetsov, R. S. Timerbulatov, N. N. Dremova, L. A. Frolova, K. J. Stevenson and P. A. Troshin, A new polytriarylamine derivative for dopant-free high-efficiency perovskite solar cells. Sustainable Energy & Fuels2019, 3, 2627–2632.
  23. D. D. Dashitsyrenova, A. G. Lvov, L. A. Frolova, A. V. Kulikov, N. N. Dremova, V. Z. Shirinian, S. M. Aldoshin, M. M. Krayushkin and P. A. Troshin, Molecular structure–electrical performance relationship for OFET-based memory elements comprising unsymmetrical photochromic diarylethenes. J. Mater. Chem. C20197, 6889–6894.
  24. L. A. Frolova, Q. Chang, S. Yu. Luchkin, D. Zhao, A. F. Akbulatov, N. N. Dremova, A. V. Ivanov, E.E. M. Chia, K. J. Stevenson and P. A. Troshin. Efficient and stable all-inorganic perovskite solar cells based on nonstoichiometric CsxPbI2Brx (x > 1) alloys. J. Mater. Chem. C2019, 7, 5314-5323.